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Synthesis of an Fe(terpy-cage)(2) dumbbell

An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an exo-position. This group can coordinate to iron(ii), yielding selectively an easy to purify Fe(terpy-cage)(2) dumbbell. The dumbbell can also be obtained in a one pot reaction, which proceeded without...

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Detalles Bibliográficos
Autores principales: Dournel, Frederic, Koshan, Massoud, Woite, Philipp, Roemelt, Michael, Otte, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979284/
https://www.ncbi.nlm.nih.gov/pubmed/35425387
http://dx.doi.org/10.1039/d1ra08994c