Synthesis of an Fe(terpy-cage)(2) dumbbell

An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an exo-position. This group can coordinate to iron(ii), yielding selectively an easy to purify Fe(terpy-cage)(2) dumbbell. The dumbbell can also be obtained in a one pot reaction, which proceeded without...

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Detalles Bibliográficos
Autores principales: Dournel, Frederic, Koshan, Massoud, Woite, Philipp, Roemelt, Michael, Otte, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979284/
https://www.ncbi.nlm.nih.gov/pubmed/35425387
http://dx.doi.org/10.1039/d1ra08994c
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author Dournel, Frederic
Koshan, Massoud
Woite, Philipp
Roemelt, Michael
Otte, Matthias
author_facet Dournel, Frederic
Koshan, Massoud
Woite, Philipp
Roemelt, Michael
Otte, Matthias
author_sort Dournel, Frederic
collection PubMed
description An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an exo-position. This group can coordinate to iron(ii), yielding selectively an easy to purify Fe(terpy-cage)(2) dumbbell. The dumbbell can also be obtained in a one pot reaction, which proceeded without isolation of the exo-functionalized cage.
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spelling pubmed-89792842022-04-13 Synthesis of an Fe(terpy-cage)(2) dumbbell Dournel, Frederic Koshan, Massoud Woite, Philipp Roemelt, Michael Otte, Matthias RSC Adv Chemistry An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an exo-position. This group can coordinate to iron(ii), yielding selectively an easy to purify Fe(terpy-cage)(2) dumbbell. The dumbbell can also be obtained in a one pot reaction, which proceeded without isolation of the exo-functionalized cage. The Royal Society of Chemistry 2022-01-26 /pmc/articles/PMC8979284/ /pubmed/35425387 http://dx.doi.org/10.1039/d1ra08994c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Dournel, Frederic
Koshan, Massoud
Woite, Philipp
Roemelt, Michael
Otte, Matthias
Synthesis of an Fe(terpy-cage)(2) dumbbell
title Synthesis of an Fe(terpy-cage)(2) dumbbell
title_full Synthesis of an Fe(terpy-cage)(2) dumbbell
title_fullStr Synthesis of an Fe(terpy-cage)(2) dumbbell
title_full_unstemmed Synthesis of an Fe(terpy-cage)(2) dumbbell
title_short Synthesis of an Fe(terpy-cage)(2) dumbbell
title_sort synthesis of an fe(terpy-cage)(2) dumbbell
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979284/
https://www.ncbi.nlm.nih.gov/pubmed/35425387
http://dx.doi.org/10.1039/d1ra08994c
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