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Bonding and stability of dinitrogen-bonded donor base-stabilized Si(0)/Ge(0) species [(cAAC(Me)–Si/Ge)(2)(N(2))]: EDA-NOCV analysis

Recently, dinitrogen (N(2)) binding and its activation have been achieved by non-metal compounds like intermediate cAAC-borylene as (cAAC)(2)(B-Dur)(2)(N(2)) [cAAC = cyclic alkyl(amino) carbene; Dur = aryl group, 2,3,5,6-tetramethylphenyl; B-Dur = borylene]. It has attracted a lot of scientific atte...

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Detalles Bibliográficos
Autores principales: Karnamkkott, Harsha S., Gorantla, Sai Manoj N. V. T., Devi, Kavita, Tiwari, Geetika, Mondal, Kartik Chandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981037/
https://www.ncbi.nlm.nih.gov/pubmed/35425464
http://dx.doi.org/10.1039/d1ra07714g