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Reversible On/Off Switching of Lactide Cyclopolymerization with a Redox-Active Formazanate Ligand

[Image: see text] Redox-switching of a formazanate zinc catalyst in ring-opening polymerization (ROP) of lactide is described. Using a redox-active ligand bound to an inert metal ion (Zn(2+)) allows modulation of the catalytic activity by reversible reduction/oxidation chemistry at a purely organic...

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Detalles Bibliográficos
Autores principales: de Vries, Folkert, Otten, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981207/
https://www.ncbi.nlm.nih.gov/pubmed/35391903
http://dx.doi.org/10.1021/acscatal.1c05689