Disentangling the Puzzling Regiochemistry of Thiol Addition to o-Quinones

[Image: see text] The addition of thiol compounds to o-quinones, as exemplified by the biologically relevant conjugation of cysteine to dopaquinone, displays an anomalous 1,6-type regiochemistry compared to the usual 1,4-nucleophilic addition, for example, by amines, which has so far eluded intensiv...

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Detalles Bibliográficos
Autores principales: Alfieri, Maria L., Cariola, Alice, Panzella, Lucia, Napolitano, Alessandra, d’Ischia, Marco, Valgimigli, Luca, Crescenzi, Orlando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981336/
https://www.ncbi.nlm.nih.gov/pubmed/35266705
http://dx.doi.org/10.1021/acs.joc.1c02911

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981336/
https://www.ncbi.nlm.nih.gov/pubmed/35266705
http://dx.doi.org/10.1021/acs.joc.1c02911

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