Catalytic behaviour of the Cu(i)/L/TEMPO system for aerobic oxidation of alcohols – a kinetic and predictive model

Here, we disclose a new copper(i)-Schiff base complex series for selective oxidation of primary alcohols to aldehydes under benign conditions. The catalytic protocol involves 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO), N-methylimidazole (NMI), ambient air, acetonitrile, and room temperature. This...

Descripción completa

Detalles Bibliográficos
Autores principales: Al-Hunaiti, Afnan, Abu-Radaha, Batool, Wraith, Darren, Repo, Timo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8982218/
https://www.ncbi.nlm.nih.gov/pubmed/35424759
http://dx.doi.org/10.1039/d1ra09359b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8982218/
https://www.ncbi.nlm.nih.gov/pubmed/35424759
http://dx.doi.org/10.1039/d1ra09359b

Ejemplares similares