N-Heterocyclic carbene (NHC)-catalyzed oxidation of unactivated aldimines to amides via imine umpolung under aerobic conditions

Herein, we disclose an NHC-catalyzed aerobic oxidation of unactivated aldimines for the synthesis of amides via umpolung of imines proceeding through an aza-Breslow intermediate. We have developed an eco-friendly method for the conversion of imines to amides by using molecular oxygen in air as the s...

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Detalles Bibliográficos
Autores principales: Ramarao, Jakkula, Yadav, Sanjay, Satyam, Killari, Suresh, Surisetti
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8982222/
https://www.ncbi.nlm.nih.gov/pubmed/35424774
http://dx.doi.org/10.1039/d2ra00897a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8982222/
https://www.ncbi.nlm.nih.gov/pubmed/35424774
http://dx.doi.org/10.1039/d2ra00897a

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