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Spontaneous in situ generation of photoemissive aurophilic oligomers in water solution based on the 2-thiocytosine ligand

Complexes [Au(S-2-thiocytosinate)(PMe(3))] (2, 2-thiocytosine = 4-amino-2-mercaptopyrimidine) and [Au(S-2-thiocytosine)(PMe(3))](CF(3)CO(2)) (3) have been prepared by the reaction of [Au(acac)(PMe(3))] (1, acac = acetylacetonate) or [Au(OCOCF(3))(PMe(3))] with 2-thiocytosine, respectively. The equim...

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Detalles Bibliográficos
Autores principales: Blasco, Daniel, Rodríguez-Castillo, María, Olmos, M. Elena, Monge, Miguel, López-de-Luzuriaga, José M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8984931/
https://www.ncbi.nlm.nih.gov/pubmed/35424821
http://dx.doi.org/10.1039/d2ra00368f