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Theoretical study of a derivative of chlorophosphine with aliphatic and aromatic Grignard reagents: S(N)2@P or the novel S(N)2@Cl followed by S(N)2@C?

The proposed S(N)2 reactions of a hindered organophosphorus reactant with aliphatic and aromatic nucleophiles [Ye et al., Org. Lett., 2017, 19, 5384–5387] were studied theoretically in order to explain the observed stereochemistry of the products. Our computations (using B3LYP as the functional) ind...

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Detalles Bibliográficos
Autores principales: Savoo, Nandini, Rhyman, Lydia, Ramasami, Ponnadurai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985194/
https://www.ncbi.nlm.nih.gov/pubmed/35424871
http://dx.doi.org/10.1039/d2ra00258b