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Theoretical study of a derivative of chlorophosphine with aliphatic and aromatic Grignard reagents: S(N)2@P or the novel S(N)2@Cl followed by S(N)2@C?
The proposed S(N)2 reactions of a hindered organophosphorus reactant with aliphatic and aromatic nucleophiles [Ye et al., Org. Lett., 2017, 19, 5384–5387] were studied theoretically in order to explain the observed stereochemistry of the products. Our computations (using B3LYP as the functional) ind...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985194/ https://www.ncbi.nlm.nih.gov/pubmed/35424871 http://dx.doi.org/10.1039/d2ra00258b |