Facile conversion of ammonia to a nitride in a rhenium system that cleaves dinitrogen

Rhenium complexes with aliphatic PNP pincer ligands have been shown to be capable of reductive N(2) splitting to nitride complexes. However, the conversion of the resulting nitride to ammonia has not been observed. Here, the thermodynamics and mechanism of the hypothetical N–H bond forming steps are...

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Detalles Bibliográficos
Autores principales: Connor, Gannon P., Delony, Daniel, Weber, Jeremy E., Mercado, Brandon Q., Curley, Julia B., Schneider, Sven, Mayer, James M., Holland, Patrick L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985503/
https://www.ncbi.nlm.nih.gov/pubmed/35440977
http://dx.doi.org/10.1039/d1sc04503b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985503/
https://www.ncbi.nlm.nih.gov/pubmed/35440977
http://dx.doi.org/10.1039/d1sc04503b

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