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Facile conversion of ammonia to a nitride in a rhenium system that cleaves dinitrogen
Rhenium complexes with aliphatic PNP pincer ligands have been shown to be capable of reductive N(2) splitting to nitride complexes. However, the conversion of the resulting nitride to ammonia has not been observed. Here, the thermodynamics and mechanism of the hypothetical N–H bond forming steps are...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985503/ https://www.ncbi.nlm.nih.gov/pubmed/35440977 http://dx.doi.org/10.1039/d1sc04503b |