Hydridotetrylene [Ar*EH] (E = Ge, Sn, Pb) coordination at tantalum, tungsten, and zirconium

In a reaction of tantalocene trihydride with the low valent aryl tin cation [Ar*Sn(C(6)H(6))][Al(OC{CF(3)}(3))(4)] (1a) the hydridostannylene complex [Cp(2)TaH(2)–Sn(H)Ar*][Al(OC{CF(3)}(3))(4)] (2) was synthesized. Hydride bridged adducts [Cp(2)WH(2)EAr*][Al(OC{CF(3)}(3))(4)] (E = Sn 3a, Pb 3b) were...

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Detalles Bibliográficos
Autores principales: Widemann, Max, Jeggle, Sebastian, Auer, Maximilian, Eichele, Klaus, Schubert, Hartmut, Sindlinger, Christian P., Wesemann, Lars
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985505/
https://www.ncbi.nlm.nih.gov/pubmed/35440987
http://dx.doi.org/10.1039/d2sc00297c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985505/
https://www.ncbi.nlm.nih.gov/pubmed/35440987
http://dx.doi.org/10.1039/d2sc00297c

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