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Hydridotetrylene [Ar*EH] (E = Ge, Sn, Pb) coordination at tantalum, tungsten, and zirconium
In a reaction of tantalocene trihydride with the low valent aryl tin cation [Ar*Sn(C(6)H(6))][Al(OC{CF(3)}(3))(4)] (1a) the hydridostannylene complex [Cp(2)TaH(2)–Sn(H)Ar*][Al(OC{CF(3)}(3))(4)] (2) was synthesized. Hydride bridged adducts [Cp(2)WH(2)EAr*][Al(OC{CF(3)}(3))(4)] (E = Sn 3a, Pb 3b) were...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985505/ https://www.ncbi.nlm.nih.gov/pubmed/35440987 http://dx.doi.org/10.1039/d2sc00297c |