Thioether-enabled palladium-catalyzed atroposelective C–H olefination for N–C and C–C axial chirality

Thioethers allowed for highly atroposelective C–H olefinations by a palladium/chiral phosphoric acid catalytic system under ambient air. Both N–C and C–C axial chiral (hetero)biaryls were successfully constructed, leading to a broad range of axially chiral N-aryl indoles and biaryls with excellent e...

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Detalles Bibliográficos
Autores principales: Li, Yanjun, Liou, Yan-Cheng, Chen, Xinran, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985512/
https://www.ncbi.nlm.nih.gov/pubmed/35440980
http://dx.doi.org/10.1039/d2sc00748g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985512/
https://www.ncbi.nlm.nih.gov/pubmed/35440980
http://dx.doi.org/10.1039/d2sc00748g

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