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Paramagnetic relaxation enhancement NMR as a tool to probe guest binding and exchange in metallohosts

Paramagnetic metallohost systems can bind guest molecules and find application as biomimetic catalysts. Due to the presence of the paramagnetic metal center, rigorous characterization of these systems by NMR spectroscopy can be very difficult. We report here that metallohost-guest systems can be stu...

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Detalles Bibliográficos
Autores principales: Swartjes, Anne, White, Paul B., Bruekers, Jeroen P. J., Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8986849/
https://www.ncbi.nlm.nih.gov/pubmed/35388004
http://dx.doi.org/10.1038/s41467-022-29406-1