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Co-ligand triphenylphosphine/alkynyl-stabilized undecagold nanocluster with a capped crown structure

We report the synthesis and crystal structure of novel co-ligand phosphine/alkynyl protected Au nanoclusters, with composition [Au(11)(PPh(3))(8)(C[triple bond, length as m-dash]CPh–CF(3))(2)](SbF(6)) (1). The gold atoms in the cluster as a capped crown structure subtend C(3v) symmetry with one deri...

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Detalles Bibliográficos
Autores principales: Gao, Yan-Li, Bi, Shiqing, Wang, Yufei, Li, Jian, Su, Ting, Gao, Xuchun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8989085/
https://www.ncbi.nlm.nih.gov/pubmed/35425070
http://dx.doi.org/10.1039/d2ra01080a