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Dramatically Increased Binding Constant of Water-Soluble Cyclodextrin Hyperbranched Polymers: Explored with Diffusion Ordered NMR Spectroscopy (DOSY)
[Image: see text] We report that the polymerization of cyclodextrin (CD) with epichlorohydrin (ECH) dramatically increases the binding constant of CD to vanillin, from 55 to 8.4 × 10(3) M(–1), by approximately 100 times, as determined by diffusion ordered spectroscopy (DOSY)–(1)H NMR. The binding co...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8991930/ https://www.ncbi.nlm.nih.gov/pubmed/35415377 http://dx.doi.org/10.1021/acsomega.1c06194 |