Dramatically Increased Binding Constant of Water-Soluble Cyclodextrin Hyperbranched Polymers: Explored with Diffusion Ordered NMR Spectroscopy (DOSY)

[Image: see text] We report that the polymerization of cyclodextrin (CD) with epichlorohydrin (ECH) dramatically increases the binding constant of CD to vanillin, from 55 to 8.4 × 10(3) M(–1), by approximately 100 times, as determined by diffusion ordered spectroscopy (DOSY)–(1)H NMR. The binding co...

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Detalles Bibliográficos
Autores principales: Doan, Anh Thi Ngoc, Doan, Van Thi Hong, Katsuki, Jun, Fujii, Shota, Kono, Hiroyuki, Sakurai, Kazuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8991930/
https://www.ncbi.nlm.nih.gov/pubmed/35415377
http://dx.doi.org/10.1021/acsomega.1c06194

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