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Synthesis and Vibrational Circular Dichroism Analysis of N-Heterocyclic Carbene Precursors Containing Remote Chirality Centers

VCD analysis of 16 diastereomeric pairs of NHC precursors containing two isolated chirality centers and different substitution patterns identified VCD transitions characteristic of the chirality center in the imidazolium ring or in the side chain, which, in contrast to ECD and OR, could be utilized...

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Detalles Bibliográficos
Autores principales: Szabó, Zita, Paczal, Attila, Kovács, Tibor, Mándi, Attila, Kotschy, Andras, Kurtán, Tibor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8999040/
https://www.ncbi.nlm.nih.gov/pubmed/35408831
http://dx.doi.org/10.3390/ijms23073471