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Hydrogenation of β-Keto Sulfones to β-Hydroxy Sulfones with Alkyl Aluminum Compounds: Structure of Intermediate Hydroalumination Products

β-Hydroxy sulfones are important in organic synthesis. The simplest method of β-hydroxy sulfones synthesis is the hydrogenation of β-keto sulfones. Herein, we report the reducing properties of alkyl aluminum compounds R(3)Al (R = Et, i-Bu, n-Bu, t-Bu and n-Hex); i-Bu(2)AlH; Et(2)AlCl and EtAlCl(2) i...

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Detalles Bibliográficos
Autores principales: Kotecki, Michał, Ochal, Zbigniew, Socha, Paweł, Szejko, Vadim, Dobrzycki, Łukasz, Stypik, Mariola, Ziemkowska, Wanda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000326/
https://www.ncbi.nlm.nih.gov/pubmed/35408758
http://dx.doi.org/10.3390/molecules27072357