Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation

A series of manganese complexes bearing an anionic pyrrole-based PNP-type pincer ligand and an anionic benzene-based PCP-type pincer ligand is synthesized and characterized. The reactivity of these complexes toward ammonia formation and silylamine formation from dinitrogen under mild conditions is e...

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Detalles Bibliográficos
Autores principales: Kuriyama, Shogo, Wei, Shenglan, Kato, Takeru, Nishibayashi, Yoshiaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000597/
https://www.ncbi.nlm.nih.gov/pubmed/35408764
http://dx.doi.org/10.3390/molecules27072373

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000597/
https://www.ncbi.nlm.nih.gov/pubmed/35408764
http://dx.doi.org/10.3390/molecules27072373

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