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Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation

A series of manganese complexes bearing an anionic pyrrole-based PNP-type pincer ligand and an anionic benzene-based PCP-type pincer ligand is synthesized and characterized. The reactivity of these complexes toward ammonia formation and silylamine formation from dinitrogen under mild conditions is e...

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Detalles Bibliográficos
Autores principales:	Kuriyama, Shogo, Wei, Shenglan, Kato, Takeru, Nishibayashi, Yoshiaki
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000597/ https://www.ncbi.nlm.nih.gov/pubmed/35408764 http://dx.doi.org/10.3390/molecules27072373

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