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Mono- and Disamarium Azacryptand Complexes: A Platform for Cooperative Rare-Earth Metal Chemistry
[Image: see text] Mono- (H(3)LSm) and disamarium complexes (LSm(2)) were prepared by reaction of the azacryptand N[(CH(2))(2)NHCH(2)-p-C(6)H(4)CH(2)NH(CH(2))(2)](3)N (H(6)L) with 1 or 2 equiv of Sm[N(SiMe(3))(2)](3), respectively. The disamarium complex features free coordination sites on both metal...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9006214/ https://www.ncbi.nlm.nih.gov/pubmed/35343681 http://dx.doi.org/10.1021/acs.inorgchem.1c03989 |