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Catalytic alkene skeletal modification for the construction of fluorinated tertiary stereocenters
Herein we describe the first construction of fluorinated tertiary stereocenters based on an alkene C(sp(2))–C(sp(2)) bond cleavage. The new process, that takes advantage of a Rh-catalyzed carbyne transfer, relies on a branched-selective fluorination of tertiary allyl cations and is distinguished by...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9006967/ https://www.ncbi.nlm.nih.gov/pubmed/35509472 http://dx.doi.org/10.1039/d2sc00968d |