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Electrostatic vs. inductive effects in phosphine ligand donor properties and reactivity
Enhanced rates and selectivity in enzymes are enabled in part by precisely tuned electric fields within active sites. Analogously, the use of charged groups to leverage electrostatics in molecular systems is a promising strategy to tune reactivity. However, separation of the through space and throug...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9007067/ https://www.ncbi.nlm.nih.gov/pubmed/35509471 http://dx.doi.org/10.1039/d1sc04277g |