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Iron-Catalyzed H/D Exchange of Primary Silanes, Secondary Silanes, and Tertiary Siloxanes

[Image: see text] A synthetic study into the catalytic hydrogen/deuterium (H/D) exchange of 1° silanes, 2° silanes, and 3° siloxanes is presented, facilitated by iron-β-diketiminato complexes (1a and 1b). Near-complete H/D exchange is observed for a variety of aryl- and alkyl-containing hydrosilanes...

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Detalles Bibliográficos
Autores principales: Linford-Wood, Thomas G., Mahon, Mary F., Grayson, Matthew N., Webster, Ruth L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9007460/
https://www.ncbi.nlm.nih.gov/pubmed/35433105
http://dx.doi.org/10.1021/acscatal.2c00224