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1,1,3,3-Tetramethylguanidine-Mediated Zwitterionic Ring-Opening Polymerization of Sarcosine-Derived N-Thiocarboxyanhydride toward Well-Defined Polysarcosine

[Image: see text] Zwitterionic ring-opening polymerization (ZROP) of sarcosine-derived N-thiocarboxyanhydrides (Me-NNTAs) can be induced by using 1,1,3,3-tetramethylguanidine (TMG) initiators in CH(2)Cl(2) at 25 °C, rapidly producing well-defined polysarcosine polymers with controlled molecular weig...

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Detalles Bibliográficos
Autores principales: Siefker, David, Chan, Brandon A., Zhang, Meng, Nho, Ju-Woo, Zhang, Donghui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9011146/
https://www.ncbi.nlm.nih.gov/pubmed/35444344
http://dx.doi.org/10.1021/acs.macromol.1c02472