Highly Selective Synthesis of Seven-Membered Azaspiro Compounds by a Rh(I)-Catalyzed Cycloisomerization/Diels–Alder Cascade of 1,5-Bisallenes

[Image: see text] The synthesis of spiro compounds featuring seven- and six-membered rings in the spirobicyclic motif is successfully achieved through a cascade process encompassing a rhodium(I)-catalyzed cycloisomerization followed by a highly selective Diels–Alder homodimerization. The scope of th...

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Detalles Bibliográficos
Autores principales: Vila, Jordi, Solà, Miquel, Pla-Quintana, Anna, Roglans, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9016767/
https://www.ncbi.nlm.nih.gov/pubmed/35324177
http://dx.doi.org/10.1021/acs.joc.2c00065

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9016767/
https://www.ncbi.nlm.nih.gov/pubmed/35324177
http://dx.doi.org/10.1021/acs.joc.2c00065

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