The stability of covalent dative bond significantly increases with increasing solvent polarity

It is generally expected that a solvent has only marginal effect on the stability of a covalent bond. In this work, we present a combined computational and experimental study showing a surprising stabilization of the covalent/dative bond in Me(3)NBH(3) complex with increasing solvent polarity. The r...

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Detalles Bibliográficos
Autores principales: Lo, Rabindranath, Manna, Debashree, Lamanec, Maximilián, Dračínský, Martin, Bouř, Petr, Wu, Tao, Bastien, Guillaume, Kaleta, Jiří, Miriyala, Vijay Madhav, Špirko, Vladimír, Mašínová, Anna, Nachtigallová, Dana, Hobza, Pavel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9018688/
https://www.ncbi.nlm.nih.gov/pubmed/35440662
http://dx.doi.org/10.1038/s41467-022-29806-3

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9018688/
https://www.ncbi.nlm.nih.gov/pubmed/35440662
http://dx.doi.org/10.1038/s41467-022-29806-3

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