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The stability of covalent dative bond significantly increases with increasing solvent polarity
It is generally expected that a solvent has only marginal effect on the stability of a covalent bond. In this work, we present a combined computational and experimental study showing a surprising stabilization of the covalent/dative bond in Me(3)NBH(3) complex with increasing solvent polarity. The r...
| Autores principales: | , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9018688/ https://www.ncbi.nlm.nih.gov/pubmed/35440662 http://dx.doi.org/10.1038/s41467-022-29806-3 |