Skeletal Ni electrode-catalyzed C-O cleavage of diaryl ethers entails direct elimination via benzyne intermediates

Diaryl ethers undergo electrocatalytic hydrogenolysis (ECH) over skeletal Ni cathodes in a mild, aqueous process that achieves direct C-O cleavage without initial benzene ring saturation. Mechanistic studies find that aryl phenyl ethers with a single para or meta functional group (methyl, methoxy, o...

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Detalles Bibliográficos
Autores principales: Zhou, Yuting, Klinger, Grace E., Hegg, Eric L., Saffron, Christopher M., Jackson, James E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9018776/
https://www.ncbi.nlm.nih.gov/pubmed/35440551
http://dx.doi.org/10.1038/s41467-022-29555-3

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9018776/
https://www.ncbi.nlm.nih.gov/pubmed/35440551
http://dx.doi.org/10.1038/s41467-022-29555-3

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