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Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters

Copper hydrides are important hydrogenation catalysts, but their poor stability hinders the practical applications. Ligand engineering is an effective strategy to tackle this issue. An amidinate ligand, N,N′-Di(5-trifluoromethyl-2-pyridyl)formamidinate (Tf-dpf) with four N-donors has been applied as...

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Detalles Bibliográficos
Autores principales: Liu, Chun-Yu, Yuan, Shang-Fu, Wang, Song, Guan, Zong-Jie, Jiang, De-en, Wang, Quan-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9018778/
https://www.ncbi.nlm.nih.gov/pubmed/35440582
http://dx.doi.org/10.1038/s41467-022-29819-y