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A site-differentiated [4Fe–4S] cluster controls electron transfer reactivity of Clostridium acetobutylicum [FeFe]-hydrogenase I

One of the many functions of reduction–oxidation (redox) cofactors is to mediate electron transfer in biological enzymes catalyzing redox-based chemical transformation reactions. There are numerous examples of enzymes that utilize redox cofactors to form electron transfer relays to connect catalytic...

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Detalles Bibliográficos
Autores principales: Lubner, Carolyn E., Artz, Jacob H., Mulder, David W., Oza, Aisha, Ward, Rachel J., Williams, S. Garrett, Jones, Anne K., Peters, John W., Smalyukh, Ivan I., Bharadwaj, Vivek S., King, Paul W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9019909/
https://www.ncbi.nlm.nih.gov/pubmed/35656134
http://dx.doi.org/10.1039/d1sc07120c