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Carbon–chalcogen bond formation initiated by [Al(NON(Dipp))(E)](−) anions containing Al–E{16} (E{16} = S, Se) multiple bonds

Multiply-bonded main group metal compounds are of interest as a new class of reactive species able to activate and functionalize a wide range of substrates. The aluminium sulfido compound K[Al(NON(Dipp))(S)] (NON(Dipp) = [O(SiMe(2)NDipp)(2)](2−), Dipp = 2,6-(i)Pr(2)C(6)H(3)), completing the series o...

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Detalles Bibliográficos
Autores principales: Evans, Matthew J., Anker, Mathew D., McMullin, Claire L., Neale, Samuel E., Rajabi, Nasir A., Coles, Martyn P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9020183/
https://www.ncbi.nlm.nih.gov/pubmed/35656129
http://dx.doi.org/10.1039/d2sc01064j