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Catalytic One-Handed Helix Induction and Subsequent Static Memory of Poly(biphenylylacetylene)s Assisted by a Small Amount of Carboxy Groups Introduced at the Pendants

[Image: see text] A dynamically racemic helical copolymer composed of an achiral biphenylylacetylene (BPA) bearing methoxymethoxy groups at the 2,2′-positions and 1 mol % of an achiral BPA carrying 2-carboxy-2′-methoxymethoxy groups at the biphenyl pendants was found to fold into an excess one-hande...

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Detalles Bibliográficos
Autores principales: Ikai, Tomoyuki, Takeda, Shoki, Yashima, Eiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9022430/
https://www.ncbi.nlm.nih.gov/pubmed/35575344
http://dx.doi.org/10.1021/acsmacrolett.2c00136