DFT Mechanistic Study of the Cyclopropanation of Styrene and Aryldiazodiacetate Catalyzed by Tris(pentafluorophenyl)borane

[Image: see text] Metal-free boron Lewis acids, tris(pentafluorophenyl)borane B(C(6)F(5))(3), have the advantages of low toxicity and low cost and are a promising catalyst. A density functional theory (DFT) calculation was used to clarify the mechanism and the origin of the diastereoselective cyclop...

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Detalles Bibliográficos
Autores principales: Wen, Xiuling, Lu, Peiquan, Shen, Yong, Peng, Haojie, Ke, Zhuofeng, Zhao, Cunyuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9025995/
https://www.ncbi.nlm.nih.gov/pubmed/35474821
http://dx.doi.org/10.1021/acsomega.2c00200

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9025995/
https://www.ncbi.nlm.nih.gov/pubmed/35474821
http://dx.doi.org/10.1021/acsomega.2c00200

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