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DFT Mechanistic Study of the Cyclopropanation of Styrene and Aryldiazodiacetate Catalyzed by Tris(pentafluorophenyl)borane
[Image: see text] Metal-free boron Lewis acids, tris(pentafluorophenyl)borane B(C(6)F(5))(3), have the advantages of low toxicity and low cost and are a promising catalyst. A density functional theory (DFT) calculation was used to clarify the mechanism and the origin of the diastereoselective cyclop...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9025995/ https://www.ncbi.nlm.nih.gov/pubmed/35474821 http://dx.doi.org/10.1021/acsomega.2c00200 |