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[Sulfonylbis(bromomethylene)]dibenzene
The title compound, C(14)H(12)Br(2)O(2)S, crystallizes as the meso isomer of a diastereoisomeric pair. This structure determination was key to determining that the 1,3 elimination of bromine by triphenylphosphine occurs with inversion of the configuration at each of the two chiral carbon atoms. In...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028549/ https://www.ncbi.nlm.nih.gov/pubmed/36337089 http://dx.doi.org/10.1107/S2414314621013511 |