[Sulfonyl­bis­(bromo­methyl­ene)]di­benzene

The title compound, C(14)H(12)Br(2)O(2)S, crystallizes as the meso isomer of a diastereoisomeric pair. This structure determination was key to determining that the 1,3 elimination of bromine by tri­phenyl­phosphine occurs with inversion of the configuration at each of the two chiral carbon atoms. In...

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Detalles Bibliográficos
Autor principal: Corfield, Peter W. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028549/
https://www.ncbi.nlm.nih.gov/pubmed/36337089
http://dx.doi.org/10.1107/S2414314621013511
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author Corfield, Peter W. R.
author_facet Corfield, Peter W. R.
author_sort Corfield, Peter W. R.
collection PubMed
description The title compound, C(14)H(12)Br(2)O(2)S, crystallizes as the meso isomer of a diastereoisomeric pair. This structure determination was key to determining that the 1,3 elimination of bromine by tri­phenyl­phosphine occurs with inversion of the configuration at each of the two chiral carbon atoms. In the crystal, the molecules are linked by weak C—H⋯O and C—H⋯Br hydrogen bonds. [Image: see text]
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spelling pubmed-90285492022-11-04 [Sulfonyl­bis­(bromo­methyl­ene)]di­benzene Corfield, Peter W. R. IUCrdata Data Reports The title compound, C(14)H(12)Br(2)O(2)S, crystallizes as the meso isomer of a diastereoisomeric pair. This structure determination was key to determining that the 1,3 elimination of bromine by tri­phenyl­phosphine occurs with inversion of the configuration at each of the two chiral carbon atoms. In the crystal, the molecules are linked by weak C—H⋯O and C—H⋯Br hydrogen bonds. [Image: see text] International Union of Crystallography 2022-01-07 /pmc/articles/PMC9028549/ /pubmed/36337089 http://dx.doi.org/10.1107/S2414314621013511 Text en © Peter W. R. Corfield 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Corfield, Peter W. R.
[Sulfonyl­bis­(bromo­methyl­ene)]di­benzene
title [Sulfonyl­bis­(bromo­methyl­ene)]di­benzene
title_full [Sulfonyl­bis­(bromo­methyl­ene)]di­benzene
title_fullStr [Sulfonyl­bis­(bromo­methyl­ene)]di­benzene
title_full_unstemmed [Sulfonyl­bis­(bromo­methyl­ene)]di­benzene
title_short [Sulfonyl­bis­(bromo­methyl­ene)]di­benzene
title_sort [sulfonyl­bis­(bromo­methyl­ene)]di­benzene
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028549/
https://www.ncbi.nlm.nih.gov/pubmed/36337089
http://dx.doi.org/10.1107/S2414314621013511
work_keys_str_mv AT corfieldpeterwr sulfonylbisbromomethylenedibenzene

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