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Dual utility of a single diphosphine–ruthenium complex: a precursor for new complexes and, a pre-catalyst for transfer-hydrogenation and Oppenauer oxidation

The diphosphine–ruthenium complex, [Ru(dppbz)(CO)(2)Cl(2)] (dppbz = 1,2-bis(diphenylphosphino)benzene), where the two carbonyls are mutually cis and the two chlorides are trans, has been found to serve as an efficient precursor for the synthesis of new complexes. In [Ru(dppbz)(CO)(2)Cl(2)] one of th...

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Detalles Bibliográficos
Autores principales: Mukherjee, Aparajita, Bhattacharya, Samaresh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9029466/
https://www.ncbi.nlm.nih.gov/pubmed/35481203
http://dx.doi.org/10.1039/d1ra01594j