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Boron-catalyzed dehydrative allylation of 1,3-diketones and β-ketone esters with 1,3-diarylallyl alcohols in water

A metal-free catalytic allylation with atom economy and green environment friendly was developed. Allylic alcohols could be directly dehydrated in water by B(C(6)F(5))(3), without using any base additives. The reaction can afford the corresponding monoallylated product in moderate to high yield and...

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Detalles Bibliográficos
Autores principales: Zhang, Guo-Min, Zhang, Hua, Wang, Bei, Wang, Ji-Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9031380/
https://www.ncbi.nlm.nih.gov/pubmed/35479693
http://dx.doi.org/10.1039/d1ra01922h