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Light-driven selective aerobic oxidation of (iso)quinoliniums and related heterocycles

Selective C1–H/C4–H carbonylation of N-methylene iminium salts, catalyzed by visible-light photoredox and oxygen in the air, has been reported. A ruthenium complex acts as a chemical switch to conduct two different reaction pathways and to afford two different kinds of products. In the absence of th...

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Detalles Bibliográficos
Autores principales: Zhou, Meimei, Yu, Keyang, Liu, Jianxin, Shi, Weimei, Pan, Yingming, Tang, Haitao, Peng, Xiangjun, Liu, Qian, Wang, Hengshan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9031974/
https://www.ncbi.nlm.nih.gov/pubmed/35479138
http://dx.doi.org/10.1039/d1ra01226f