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The graphite-catalyzed ipso-functionalization of arylboronic acids in an aqueous medium: metal-free access to phenols, anilines, nitroarenes, and haloarenes

An efficient, metal-free, and sustainable strategy has been described for the ipso-functionalization of phenylboronic acids using air as an oxidant in an aqueous medium. A range of carbon materials has been tested as carbocatalysts. To our surprise, graphite was found to be the best catalyst in term...

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Detalles Bibliográficos
Autores principales: Dandia, Anshu, Sharma, Ruchi, Saini, Pratibha, Badgoti, Ranveer Singh, Rathore, Kuldeep S., Parewa, Vijay
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033238/
https://www.ncbi.nlm.nih.gov/pubmed/35480165
http://dx.doi.org/10.1039/d1ra01940f