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Visible-light enabled room-temperature dealkylative imidation of secondary and tertiary amines promoted by aerobic ruthenium catalysis

Employing sulfonyl azide as a nitrogen donor, a visible-light-enabled aerobic dealkylative imidation of tertiary and secondary amines involving C(sp(3))–C(sp(3)) bond cleavage with moderate to excellent yields at room temperature is described. It has been demonstrated that this imidation could take...

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Detalles Bibliográficos
Autores principales: Yang, Dong, Shi, Jingqi, Chen, Jiaming, Jia, Xiaoqi, Shi, Cuiying, Ma, Lifang, Li, Ziyuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033495/
https://www.ncbi.nlm.nih.gov/pubmed/35478631
http://dx.doi.org/10.1039/d0ra10517a