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Copolymers of bipyridinium and metal (Zn & Ni) porphyrin derivatives; theoretical insights and electrochemical activity towards CO(2)

This study reports the electropolymerization of novel keto functionalized octaethyl metal porphyrins (Zn(2+) and Ni(2+)) in the presence of 4,4′-bipyridine (4,4′-bpy) as a bridging nucleophile. The polymer films were characterized by electrochemical, spectroscopic (UV-Vis, XPS, FT-IR and Raman spect...

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Detalles Bibliográficos
Autores principales: Kochrekar, Sachin, Kalekar, Ajit, Mehta, Shweta, Damlin, Pia, Salomäki, Mikko, Granroth, Sari, Meltola, Niko, Joshi, Kavita, Kvarnström, Carita
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033822/
https://www.ncbi.nlm.nih.gov/pubmed/35479229
http://dx.doi.org/10.1039/d1ra01945g