Mechanistic insight into B(C(6)F(5))(3) catalyzed imine reduction with PhSiH(3) under stoichiometric water conditions

A DFT and experimental study on the mechanism of B(C(6)F(5))(3) catalyzed imine reduction is performed using PhSiH(3) as reductant under stoichiometric water conditions. Ingleson’s path B is reconfirmed here. And four novel (C(6)F(5))(3)B–OH(2) induced pathways (paths C2, C3, D2 and D3) entirely dif...

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Detalles Bibliográficos
Autores principales: He, Yunqing, Nie, Wanli, Xue, Ying, Hu, Qishan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034009/
https://www.ncbi.nlm.nih.gov/pubmed/35479343
http://dx.doi.org/10.1039/d1ra02399c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034009/
https://www.ncbi.nlm.nih.gov/pubmed/35479343
http://dx.doi.org/10.1039/d1ra02399c

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