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Mechanistic insight into B(C(6)F(5))(3) catalyzed imine reduction with PhSiH(3) under stoichiometric water conditions
A DFT and experimental study on the mechanism of B(C(6)F(5))(3) catalyzed imine reduction is performed using PhSiH(3) as reductant under stoichiometric water conditions. Ingleson’s path B is reconfirmed here. And four novel (C(6)F(5))(3)B–OH(2) induced pathways (paths C2, C3, D2 and D3) entirely dif...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034009/ https://www.ncbi.nlm.nih.gov/pubmed/35479343 http://dx.doi.org/10.1039/d1ra02399c |