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Bi(OTf)(3)-catalysed intramolecular cyclisation of unsaturated acetals

A series of highly functionalized carbocycles was efficiently prepared via the selective cyclisation of unsaturated acetals and ketals in the presence of only 1 mol% of Bi(iii) or Fe(iii) triflates as the catalysts at room temperature, with yields ranging from 60 to 90%. With Bi(OTf)(3) catalysis, α...

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Detalles Bibliográficos
Autores principales: Saget, Raphaël, Jaunky, Piotr, Duñach, Elisabet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034051/
https://www.ncbi.nlm.nih.gov/pubmed/35479394
http://dx.doi.org/10.1039/d1ra03686f