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Acid-catalyzed transformation of cassane diterpenoids from Caesalpinia bonduc to aromatic derivatives

Transformations of cassane diterpenoids from Caesalpinia bonduc into aromatic derivatives, either in CDCl(3) or in CHCl(3) irradiated with UV light or catalyzed by AlCl(3), were described. Caesalmin C (2) was hydrolyzed with Na(2)CO(3) upon refluxing in MeOH to yield compound 1. Dissolving compound...

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Detalles Bibliográficos
Autores principales: Liu, Ting, Ning, Zunxi, Yin, Yan, Qi, Shizhou, Gao, Huiyuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034224/
https://www.ncbi.nlm.nih.gov/pubmed/35480829
http://dx.doi.org/10.1039/d1ra03636j